Thermochromism and switchable paramagnetism of cobalt(II) in thiocyanate ionic liquids.

نویسندگان

  • Stephen J Osborne
  • Sil Wellens
  • Chris Ward
  • Solveig Felton
  • Robert M Bowman
  • Koen Binnemans
  • Małgorzata Swadźba-Kwaśny
  • H Q Nimal Gunaratne
  • Peter Nockemann
چکیده

Temperature-dependent switching of paramagnetism of a cobalt(II) complex is observed in an ionic liquid solution. Paramagnetic and thermochromic switching occur simultaneously due to a reversible change in coordination. This reversible switching is possible in the ionic liquid solution, which enables mobility of thiocyanate anions by remaining mobile at low temperatures and acts as an anion reservoir.

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عنوان ژورنال:
  • Dalton transactions

دوره 44 25  شماره 

صفحات  -

تاریخ انتشار 2015